Modern Steam Engines

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Similar to hydrogen-powered vehicles, the "exhaust" produced by nanoFlowcell electric vehicles is water vapour. But are the water vapour emissions from future electric vehicles environmentally friendly?

Critics of electric mobility are increasingly questioning the environmental compatibility and sustainability of alternative energies. Many maintain that automotive electric drives represent a compromise between zero-emission driving and environmentally harmful technology. Conventional lithium-ion or metal-hydride batteries are neither sustainable nor environmentally benign — not in production, not in use, and not in recycling — even if marketing suggests clean “e-mobility.”

nanoFlowcell Holdings is likewise often asked about the sustainability and environmental compatibility of nanoFlowcell technology and the bi-ION® electrolytes. Both the nanoFlowcell unit itself and the bi-ION electrolyte solutions required to power it are produced in an environmentally compatible manner from sustainable raw materials. In operation, too, nanoFlowcell technology is completely non-toxic and harmless to health. bi-ION, which consists of a slightly saline aqueous solution (organic and mineral salts dissolved in water) plus the actual energy carriers (electrolytes), is similarly environmentally friendly in both use and recycling.

How does a nanoFlowcell drive work in an electric vehicle? Similar to a petrol-driven car, the electrolyte solution is consumed in a nanoFlowcell-powered electric vehicle. Inside the nanoFlowcell (the actual flow cell), one positively and one negatively charged electrolyte solution are pumped past a cell membrane.

QUANTiNO 48VOLT 1'176km Testdrive

A reaction — an ion exchange — takes place between the positively and negatively charged electrolyte solutions. The chemical energy contained in bi-ION® is thus released as electricity, which then drives the electric motors. This continues as long as the electrolytes are pumped past the membrane and react. In the case of the nanoFlowcell-driven QUANTiNO, one tank of electrolyte liquid is sufficient for more than 1,000 kilometres. Once depleted, the tank must be refilled.

What “waste products” are generated by a nanoFlowcell-driven electric vehicle? In a conventional internal combustion engine, the combustion of fossil fuels (petrol or diesel) produces hazardous exhaust gases — primarily carbon dioxide, nitrogen oxides and sulphur dioxide — which many researchers identify as causes of climate change. However, the only emissions from a nanoFlowcell vehicle during driving consist — much like with a hydrogen-powered vehicle — almost entirely of water.

After ion exchange in the nanoFlowcell, the chemical composition of the bi-ION® electrolyte solution remains virtually unchanged. It becomes non-reactive and is thus considered “spent,” since it cannot be recharged. For mobile applications of nanoFlowcell technology such as electric vehicles, the chosen solution is to microscopically vaporise and release the consumed electrolyte while driving. At speeds above 80 km/h, the holding tank for the spent electrolyte liquid is emptied via ultra-fine spray nozzles driven by a generator powered by the drive system. The electrolytes and salts are filtered mechanically in advance. The now cleanly filtered water is released as cold water vapour (a micro-fine mist) in an entirely environmentally compatible manner. The filter is replaced at approximately 10,000 km intervals, and its disposal is equally environmentally benign.

The advantage of this technical solution is that the vehicle’s tank empties while driving as usual and can be refilled conveniently and quickly — without needing to pump out beforehand.

An alternative approach, marginally more complex, would be to collect the “spent” electrolyte solution in a separate tank and send it for recycling. This solution is envisioned for stationary nanoFlowcell applications.

However, many critics now argue that water vapour — whether from hydrogen conversion in fuel cells or via vaporisation of electrolyte liquid (as with nanoFlowcell) — is theoretically a greenhouse gas and could influence climate change. How do such claims arise?

We assess water vapour emissions in terms of environmental relevance and ask how much additional water vapour might result from widespread adoption of nanoFlowcell-driven vehicles compared with conventional propulsion technologies, and whether these H₂O emissions could exert a negative environmental effect.

The greenhouse effect becomes problematic only when human intervention disturbs the natural cycle. When, in addition to naturally occurring greenhouse gases, humans release extra greenhouse gases by burning fossil fuels, the heating of Earth’s atmosphere is amplified.

As part of the biosphere, humans inevitably influence their environment—and thus the climate system—by their existence. Since the Stone Age, population growth, settlement formation, and the shift to agriculture and livestock farming have already affected climate. Nearly half of Earth’s original forests and woodlands have been cleared for agriculture. Human Domination of Earth's Ecosystems

Forests are - alongside the oceans - a main producer of water vapour.

Water vapour is the principal absorber of heat radiation in the atmosphere. It constitutes, on average, about 0.3 % by mass of the atmosphere, while carbon dioxide accounts for roughly 0.038 %. Thus, by mass, water vapour comprises about 80 % of all greenhouse gases (approximately 90 % by volume). Its share of the greenhouse effect is estimated between 36 % and 66 %, making it the most critical greenhouse gas for sustaining Earth’s surface temperature.

Substance
Atmospheric share by volume [%]
Temperature increase [°C]
H2O
2.6
20.6
CO2
0.035
7.2
O3
0.000003
2.4
N2O
0.00003
1.4
CH4
0.00017
0.8
Other
< 0.0000001
0.8
Atmospheric share of key greenhouse gases and their absolute / relative contributions to temperature increase. Source: UNFCCC (Zittel): UNFCCC

Beyond natural water vapour emissions, the greatest anthropogenic source is artificial irrigation (IPCC). Nevertheless, extensive deforestation drastically reduces the evapotranspiration that would otherwise release significant quantities of water vapour.

The anthropogenic contribution to water vapour is typically not included in climate models because, relative to natural emissions via evaporation, it’s estimated to contribute only about 0.005 % — hence it is considered negligible. In contrast, anthropogenic CO₂ emissions, constituting roughly 4 % of greenhouse gas additions, exert a significant influence on the natural atmospheric cycle. Emissionen von Wasserstofffahrzeugen

Road transport accounts for approximately 11 % of global CO₂ emissions. If vehicles emitted water vapour instead of CO₂, the climate impact would shift substantially.

The following estimates concern water vapour emissions in Germany:

  • With average annual precipitation of ~780 mm and a land area of ~360,000 km², total precipitation amounts to ~280 billion tonnes.
  • Natural water vapour emissions per km² per year are estimated at ~0.35 × 10⁶ tonnes. Across the entire area, this totals ~125,000 × 10⁶ tonnes of water vapour annually (assuming ~50 % evaporation, remainder runs off to seas).
  • If all 45.1 million passenger cars in Germany were converted to nanoFlowcell drive, and each vaporised ~1,000 litres of electrolyte per year, this would emit water vapour equivalent to ~0.01 % of Germany’s natural water vapour emissions.

On a global scale, natural evaporation — especially from oceans and forests — is so massive that anthropogenic water vapour emissions become essentially negligible (less than 0.005 %).

Furthermore, the greenhouse effect of water vapour depends significantly on atmospheric height: emissions in the stratosphere (e.g. from aircraft) have a stronger effect than near-surface emissions. The consensus in climate science is that anthropogenic water vapour emissions near the ground have negligible greenhouse potential. In contrast, water vapour emissions into the upper atmosphere constitute an additional, often invisible, greenhouse effect.

We assert that QUANTiNO and QUANT FE are not emission-free — they still produce water (plus small quantities of recyclable electrolyte and salts). But even if all vehicles worldwide used nanoFlowcell drive, the resultant water vapour emissions would not affect climate change. They would generate less water vapour than the deforested land produces annually.

As an environmentally compatible and sustainable energy source, nanoFlowcell has a positive climate role. Every electric vehicle powered by nanoFlowcell that replaces a conventional internal combustion vehicle reduces emissions of carbon oxides, nitrogen oxides and sulphur dioxide.

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